Chuck and Sarah have a communication breakdown as Awesome is reunited with someone from his brief spy past. Chuck and Sarah work on becoming better communicators as they join Awesome and Ellie for a getaway to Costa Gravas. There, the gang is reunited with Generalissimo Goya who finds himself in a dangerous situation once again. Back at home, Morgan embarks on a forbidden romance that may put him at odds with Colonel John Casey.
Zachary Levi
Chuck Bartowski
Chuck Bartowski
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Yvonne Strahovski
Sarah Walker
Sarah Walker
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Joshua Gomez
Morgan Grimes
Morgan Grimes
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Ryan McPartlin
Devon Woodcomb
Devon Woodcomb
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Bonita Friedericy
General Diane Beckman
General Diane Beckman
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Mekenna Melvin
Alex McHugh
Alex McHugh
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Armand Assante
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Premier Alejandro Goya
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Sarah Lancaster
Ellie Bartowski
Ellie Bartowski
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Adam Baldwin
John Casey
John Casey
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Todd Sherry
None
Dr. Fred Hornblower
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Tia Texada
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Hortencia Goya
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Alex Fernandez
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Commandante Juan Pablo Turrini
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| Name | Chuck Versus the Coup D'Etat |
| Season | 4 |
| Episode Number | 4 |
| Type | Regular Episode |
| Is Pilot | False |
| Air Date | Oct. 11, 2010 |